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Table 1 The constituent composition, synthetic methodology, and physicochemical properties of porphyritic MOF nanosheets

From: Two-dimensional metal-organic frameworks: from synthesis to bioapplications

Materials

2D MOFs

Methodology

Thickness (nm)

Refs.

Metal

Ligand

Zn2(PdTCPP)

Zn(NO3)2·6H2O

Intercalation and chemical exfoliation

 ~ 1

[53]

UNs-FA

ZrCl4

Solvothermal reaction

1.48 ± 0.22

[54]

Zn-TCPP(Fe)

Zn2+

Surface-assisted approach

1–1.5

[55]

Cu-TCPP(Fe)

Cu(NO3)2·3H2O

Surfactant-assisted approach

3.5 ± 1.2

[56]

M-TCPP(Fe)

Zn2+; Co2+; Cu2+

Surfactant-assisted approach

–

[57]

PPF-Gd NS

Gd3+

Surfactant-assisted approach

21.0 ± 9.4

[58]

Fe-TBP

[Fe3O(OAc)6(H2O)3]OAc

Solvothermal reaction

–

[59]

Hf-MOL

Hf12(m3-O)8(m3-OH)8 (m2-OH)6

Solvothermal reaction

1.6

[60]