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Table 4 Performance of some high sensitivity semiconductor-based SERS substrates

From: Recent development of surface-enhanced Raman scattering for biosensing

Materials

Probe molecule

LOD

EF

Refs.

GaP

Copper Phthalocyanine

N/A

7 × 102

[51]

WSe2

Copper Phthalocyanine

N/A

102

[168]

GaN

Basic Fuchsin

N/A

1 × 107

[169]

CdTe

4-Mercaptopyridine

1.8 × 10–3 M

1 × 104

[52]

InAs

Simulation calculation

N/A

1010–1011 (THz excitation)

[170]

CdSe

4-Mercaptopyridine

10–1 M

N/A

[171]

CdSe-TiO2 IOS Film

Methylene Blue

7 × 10−9 M

1.46 × 105

[172]

ZnO/Ag@Au

Rhodamine 6G

10−10 M

1.48 × 109

[173]

ZnS

4-Mercaptopyridine

9 × 10−3 M

103

[174]

ZnSe

4-Mercaptopyridine

10−3 M

2 × 106

[175]

Nb2O5

Methyl Violet

10−8 M

2.09 × 107

[176]

Ta2O5

Methyl Violet

9 × 10−9 M

2.2 × 107

[177]

TiO2

Rhodamine 6G

1 × 10−7 M

1.20 × 106

[24]

CdS

Benzenethiol

N/A

N/A

[178]

CuO

Rhodamine 6G

1 × 10−8 M

N/A

[179]

AgFeO2

Rhodamine 6G

1 × 10−7 M

5.1 × 105

[180]

ReS2

Copper Phthalocyanine

N/A

10

[181]

W18O49

Rhodamine B

1 × 10−7 M

N/A

[182]

V2O5

Rhodamine 6G

1 × 10−8 M

N/A

[183]

CuTe

Nile Red

N/A

106

[184]

Si (H-SiNWs)

Rhodamine 6G

1 × 10−6 M

102

[185]

Ge (H-GeNT)

Rhodamine 6G

1 × 10−6 M

102

[185]

Cu2O

4-Mercaptobenzoic

10–3 M

5.36 × 105

[186]

Pb3O4

4-Mercaptopyridine

10–7 M

N/A

[187]

Black Phosphorus

Crystal Violet

10–5 M

2.14 × 105

[188]

Graphene

Rhodamine B

∼10–8 M

103

[189]

MoS2

4-Mercaptopyridine

10–3 M

3 × 105

[190]

TaSe2

Rhodamine 6G

10–10 M

1.5 × 105

[191]

Ti3C2

Rhodamine 6G

10–11 M

3.82 × 108

[192]

SnS2

Methylene Blue

10–13 M

3.0 × 108

[120]

MoTe2

Rhodamine 6G

4 × 10–14 M

6.2 × 109

[193]

Ti2N

Rhodamine 6G

10–15 M

1012

[194]

Re-WSe2

Rhodamine 6G

5 × 10–15 M

2.0 × 109

[195]

WTe2

Rhodamine 6G

4 × 10–15 M

4.4 × 1010

[193]

Ag/BP

Rhodamine 6G

10–20 M

1.01 × 1011

[157]