Nanomaterials | Pollutants | Experimental conditions | qmax (mg/g) Ads kinetics | Removal efficiency (%) (L/Fa, A) | R2 | Mechanism | References | ||||
---|---|---|---|---|---|---|---|---|---|---|---|
 |  | Sorbent mg/L initial | Adsorbent dose (g/L) | Temp ( ͦ C) | pH | Time (h) |  |  |  |  |  |
Fe–Ni-Eucalyptus leaf extract | Ar | 0.8 g | 0.4–4 | 20 | 6 | 24 | 2nd | 87.3 L | 0.99 | S.C, E.R | [72] |
ZnO-Banana peel extract | Basic Blue 9, crystal violet, and cresol red | 30 | 2.0 × 10–5 M | – | 12 | 1.5 | – | 100 | – | P | [153] |
Fe (nZVI)-pomegranate peel coated activated carbon | Amoxicillin | 50 | 1 | 20 | 5 | 0.5 | 40.28 2nd | 97.9, L | 0.99 | – | [154] |
Activated carbon-Neem (Azadirachta indica) leaf extract | Ciprofloxacin | 10 | 1.2 | 30 | 4 | 3 | 2nd | 89.5 L | 0.99 | I.E, π–π, H | [155] |
Activated carbon-pomegranate husk | 4-Chlorophenol | 20 | 0.4 | 20 | 6 | 2 | 26.18, 24.78, 2nd | 100 L, A | 0.99 | H | [156] |
Chitosan-iron-activated carbon-orange peel | Nitrate | 50 | 0.1 | 20 | 2 | 3 | 263.15 2nd | 99.59 L | 1 | I.P.D | [157] |
Fe3O4-Azardica indica leaf extract | Methyl blue, 2-Nitroaniline | 140, 0.05 | 5 | 21–23 | 6.3 | 2.67 | – | 99.96, 83 | – | R | [158] |
CuO-Moringa oleifera extract | Nitrate | 100 | 0.5 | 25 | 2 | 24 | 7.98 1st | 60 L | 0.99 | E.A | [159] |
TiO2-Jatropha curcas L. leaves extract | Chemical oxygen demand (COD), Cr VI | 5000 | 6.8, 3.2 mg/L | 59 | UN | 5 | – | 82.26, 76.48 | 0.95 | P | [160] |
Cu2O-lignin | Bacteria | 10 μL | 90 μL | 37 | 7 | 24 | – | 100 | – | D | [82] |
Cu2O- astragalus, rosemary and mallow | Pb | 0.030 | 0.2 | 25 | 7 | 24 | 41.1, 39.8, 32.4, 1st | 88.4, 84.9, 69.6, L | 0.99 | Co, C | [149] |
Activated carbon- pomegranate peel- nZVI | Amoxicillin | 10Â mL | 1.5 | 25 | 5 | 0.5 | 40.28 1st | 83.54 L | 0.99 | I.P.D | [154] |
FeNPs-Korla fragrant pear peel extracts | Cr | 10 | 0.02 | 55 | 5 | 2 | 46.6, 1st | 99.1, L | 0.97 | R, C.P | [52] |
ZnO-Syzygium cumini plant leaves extract | Methylene blue | 2 mg/50 mL | 0.5 | – | 8 | 2 | 1st | 91.4 |  | P | [161] |
FeNPs-(Eucalyptus leaf extracts | Ammonia, Phosphate | 10 | 7 | 30 | 6.35 | 0.5 | 3.47, 38.91 2nd | 43.3 NH4+, 99.8 PO43−, L | 0.95–0.97 | Ch | [150] |
AgNPs-Ficus Benjamina leaf extract | Cd | 50–100 | 0.05 | 25 | 5 | 0.67 | 2nd | F | 0.97 | – | [162] |
Fe3O4-wheat straw | Hg° | 40 | 1 | 25 | 6 | 0.75 | 101.01 2nd | 98 L | 0.99 | E.A | [163] |
ZnO-Artemisia absinthium | Cr (VI) | 25 | 0.25 | 25 | 4 | 2.5 | 315.46 2nd | 99 L | 0.99 | E.A | [164] |
α-Fe2O3-Aloe vera leaf extract | Ar (V) | 10 | 0.5 | 20 | 6 | 12 | 7.95 2nd | 98, L | 0.99 | Ch | [165] |
Cu0 + Ag)@Bentonite-P. guajava leaves | Amoxicillin, Sulfamethazine | 2.0 | 0.3 | 25 | 3 | 2 | 1st | 84 and 74 | 0.98 | P | [166] |
CuO/NiO-Capparis decidua | Lambda-cyhalothrin | 20 | 0.002 | 25 | 7 | 3 | 1st | 99, 89 | Â | R, O, P | [167] |
Rice straw biochar-alginate beads | Per- and polyfluoroalkyl | 0.1 | 1 | – | 7 | 16 | 1.572 2nd | 87–99 F,L | 0.99, 0.97 | Ch | [168] |
Fe2O3 -black tea | Ametryn | 30.0 μg/L | 2.5 g/L | 20 | 7 | 0.5 | 2nd | F, L, T, D | 0.98 | L.F.D | [169] |
Fe3O4-office paper (cellulose fibre) | Cobalt oxide | 100 mg L−1 | 100 mg L−1 | 25 | 5 | 48 | 1567 2nd | L | 0.94 | Ch, E.A | [75] |